I never iron, I especially buy work clothes that won't need it. As long as I hang my work pants and skirts they're fine and I never where shirts, just buy blouses/knits that don't need ironing. The most I ever do is a touch up when absolutely necessary.
DP's work uniform (he's a cop) needs to be ironed daily, mostly because it's made from fairly cheap material and partly because he doesn't put it away properly. Lucky for me he is under the impression that I am very bad at ironing and always does his own... Not sure where he got that idea from, it is possibly true but I don't want to test it out, the current system works for me